7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. Lithium Coupon. Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. Molecular Weight 42.39 . [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. LiCl is also used as a brazing flux for aluminium in automobile parts. Linear Formula LiCl . The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air. Haz. 1989]. 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures h�b```�m���� ��ea��� �pP\������� 8��������6JˆF��ƈ����! (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. NFPA SUPPLIER Santa Cruz Biotechnology, … The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Section 1: Chemical Product and Company Identification. Blisters. Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. ��0��΁���X�D��Ai��G���ʄQ�fW��v[N�DN1���@� -L����>��anl®i�1S��{�䆬�2�Vo +�#��R\&�KᙱD��Kv ��6,m��@�[��6�Lp�!��"� ix�:�r�m1���rվ�h�yM���b�U'Cɮy]4���g�P���R�N�:�Գ���X���O���x�E)���� 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. [7] The anhydrous salt can be regenerated by heating the hydrates. Health Hazard SYMPTOMS: Symptoms of exposure to this compound may include vomiting, profuse diarrhea, ataxia, coma, convulsions and local irritation of the skin, eyes and mucous membranes. May … [6] Mono-, tri-, and pentahydrates are known. Cold water can be used. It is used as a desiccant for drying air streams. Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … Lithium chloride is a chemical compound with the formula LiCl. 1956]. Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable Gives off irritating or toxic fumes (or gases) in a fire. CAS#: 7447-41-8. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. 1:380. ��u�u��f5kx��ތ�L.���b8>φ����t6?�Lnso& ��w��" h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@؂U�H^�ja��a��+Y�� (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. eCl@ss 38050203 . Skin burns. It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). Additionally, lithium chloride can itself be used as a hygrometer. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Potential Health Effect Eye: Causes moderate eye irritation. (j) aspiration hazard Lithium chloride, a solid, does not present an aspiration hazard. D ECO #11598 P a g e 1 Material Safety Data Sheet Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries All Electrochem 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cells and Batteries Lithium chloride lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity Lithium chloride Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting Lithium chloride The information presented above is offered for informational purposes only. : 7447-41-8 Molecular Weight: 42.39 Chemical Formula: LiCl Product Codes: J.T. Info. [11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Sore throat. In case of contact with eyes, check for wearing contact lenses and remove them immediately. 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. Material Safety Data Sheet Lithium Chloride sc-203110 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Lithium Chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. "� �����6¿^=��}d �5A��h�{�sW��a� �?Mo4%BH�ף](O7�"B��»c�B�`L1�6� 1. ��c��}��M�(�Ohv�-ʿ (�s� endstream endobj 406 0 obj <>stream The salt forms crystalline hydrates, unlike the other alkali metal chlorides. Effects of exposure to Lithium: Fire: Flammable. Ph Eur - Find MSDS or SDS, a COA, data sheets and more information. h�bbd```b``��5 ��4�d���E4�lq�x-�d���K"�w�$7����3��$S�U��)�,`��1`��`���Ge �"� �#������:@� �� endstream endobj startxref 0 %%EOF 467 0 obj <>stream Large doses of lithium may cause dizziness, prostration, and kidney damage. LiCl also absorbs up to four equivalents of ammonia/mol. Molten LiCl is used for the preparation of carbon nanotubes,[9] graphene[10] and lithium niobate. MDL number MFCD00011078. �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J Ingestion: Abdominal cramps. Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. Inhalation: Burning sensation. [12], Lithium salts affect the central nervous system in a variety of ways. Lithium chloride is a chemical compound with the formula LiCl. Re: Lithium Chloride safety and alternatives CausticSymmetry on Sat Nov 14, 2015 11:23 am Pumbaa - My own success was based on internal use only, so my experience is … [�� ����x����2L��?���j7�Ea�Px���Y�sE�GՖ6�`9b��������+��$x�i�+�{��W*n˕����b��u�R��eXKV�m��@ �S��{�U The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. NACRES NA.23 safety hazards of Copper Chloride to potentially exposed workers. It is used as a dessicant. 6: … Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG׽�i��="�! Flush eyes with running water for at least 15 minutes, keeping eyelids open. 402 0 obj <> endobj 424 0 obj <>/Filter/FlateDecode/ID[<75F8B29C5E5C094E8E8A203404A1AD96>]/Index[402 66]/Info 401 0 R/Length 109/Prev 456671/Root 403 0 R/Size 468/Type/XRef/W[1 3 1]>>stream 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. No envisaged effects other than acute effects from local irritation EC Number 231-212-3. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z� �uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. lithium chloride. Skin: Redness. Material Safety Data Sheet or SDS for Lithium chloride 105679 from Merck for download or viewing in the browser. While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. }�,@����)�����H �` E0� endstream endobj 403 0 obj <>/Metadata 16 0 R/Pages 400 0 R/StructTreeRoot 22 0 R/Type/Catalog>> endobj 404 0 obj <>/MediaBox[0 0 630 810]/Parent 400 0 R/Resources<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 405 0 obj <>stream Burning sensation. F3��-�5�"���:܂���.u�N�m� '0R l�;� �ü�,���8�8�:��H�} Product Name: Lithium chloride. ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. %PDF-1.6 %���� Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. Lithium Thionyl Chloride Battery Safety Data Sheet 3 May 2017 EN (English) 5/7 Aspiration hazard : Not classified Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. Abdominal pain. Laboured breathing. If a battery ruptures, may be … COPPER CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. Lithium chloride is also used as a flame colorant to produce dark red flames. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Lithium chloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F). T n��ë��>T�u#����NF���0�L����ɷ�����&��0$�ޓ�������J���M]�y������t8xu8]����"rѮ+eմ��F��S�[}|k6�m�ټ������n�2�w:��'���� ���~�Z���W�&������6�����^���NA嘃`f=.�T�j�6� *�X��`=� Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. Causes redness and pain. This deliquescent salt forms a self-solution when exposed to air. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. Severe deep burns. Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). ��Ʉ��[H8���s\�����`���E$Y�}u1��_ Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. Series C-71. MSDS-0002 Rev. Section 3: Hazards Identification. Product Identification Synonyms: Lithium monochloride CAS No. 1960]. For a short time in the 1940s lithium chloride was manufactured as a salt substitute, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea) were recognized. Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. N… Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. LEAKING FLUID IS CORROSIVE. Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X 5�? Pain. Eyes: Redness. 1962, Chem. Symptoms may be delayed. HUMAN EXPOSURE AND TOXICITY: Acute poisoning in man reported after 4 doses of 2 g each of lithium chloride, causing weakness, prostration, vertigo, and tinnitus. ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! May cause headache, muscle weakness and incoordination, and confusion. Cough. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.[5]. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions. LITHIUM CHLORIDE . At 25 °C (77 °F) a saturated solution (45.8%) of the salt will yield an equilibrium relative humidity of 11.30%. 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